Chile defeated Australia 3 -1 in Cuiaba to take the 2nd place in the Group B standings.
Australia had a slow start, as goals from Alexis Sanchez and Jorge Valdivia saw them trail 2-0 after 14 minutes, but Tim Cahill scored at his third World Cup to get his side team into the match. The game was close until Jean Beausejour scured Chile's victory.
Stats:
| Chile | Team stats | Australia |
| 11 | Total shots | 13 |
| 9 | Shots on goal | 6 |
| 9 | Fouls | 18 |
| 62% | Possession (%) | 38% |
| 3 | Corners | 1 |
| 3 | Saves | 3 |
| 1 | Offsides | 1 |
| 0 | Red Card | 0 |
| 1 | Yellow Card | 3 |
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